2,4-Dihydroxyacetophenone

Common Name

2,4-Dihydroxyacetophenone Description

Potential component of FEMA 3662. 2,4-Dihydroxyacetophenone is a flavouring ingredient2,4-Dihydroxyacetophenone belongs to the family of Tyrosols and Derivatives. These are compounds containing an hydroxyethyl group atached to the C4 carbon of a phenol group. Structure

MOLSDF3D-SDFPDBSMILESInChI View 3D Structure

Structure for HMDB29657 (2,4'-Dihydroxyacetophenone)

Synonyms

Value Source 4-Hydroxyphenacyl alcoholChEBI 2-Hydroxy-1-(4-hydroxyphenyl)ethanone, 9ciHMDB Hydroxymethyl P-hydroxyphenyl ketoneHMDB P-HydroxybenzoylcarbinolHMDB P-Hydroxyphenacyl alcoholHMDB

Chemical Formlia

C8H8O3 Average Molecliar Weight

152.1473 Monoisotopic Molecliar Weight

152.047344122 IUPAC Name

2-hydroxy-1-(4-hydroxyphenyl)ethan-1-one Traditional Name

2,4-dihydroxyacetophenone CAS Registry Number

5706-85-4 SMILES

OCC(=O)C1=CC=C(O)C=C1

InChI Identifier

InChI=1S/C8H8O3/c9-5-8(11)6-1-3-7(10)4-2-6/h1-4,9-10H,5H2

InChI Key

KLAKIAVEMQMVBT-UHFFFAOYSA-N Chemical Taxonomy Description

This compound belongs to the class of chemical entities known as alkyl-phenylketones. These are aromatic compounds containing a ketone substituted by one alkyl group, and a phenyl group. Kingdom

Chemical entities Super Class

Organic compounds Class

Organic oxygen compounds Sub Class

Organooxygen compounds Direct Parent

Alkyl-phenylketones Alternative Parents

  • Benzoyl derivatives
  • Aryl alkyl ketones
  • 1-hydroxy-2-unsubstituted benzenoids
  • Alpha-hydroxy ketones
  • Primary alcohols
  • Organic oxides
  • Hydrocarbon derivatives
  • Substituents

  • Alkyl-phenylketone
  • Aryl alkyl ketone
  • Benzoyl
  • 1-hydroxy-2-unsubstituted benzenoid
  • Phenol
  • Benzenoid
  • Monocyclic benzene moiety
  • Alpha-hydroxy ketone
  • Organic oxide
  • Hydrocarbon derivative
  • Primary alcohol
  • Alcohol
  • Aromatic homomonocyclic compound
  • Molecliar Framework

    Aromatic homomonocyclic compounds External Descriptors

  • phenols (CHEBI:35164 )
  • dihydroxyacetophenone (CHEBI:35164 )
  • a small moleclie (CPD-242 )
  • Ontology Status

    Expected but not Quantified Origin

  • Endogenous
  • Food
  • Biofunction

    Not Available Application

  • Flavoring Agent
  • Cellliar locations

  • Cytoplasm
  • Extracellliar
  • Physical Properties State

    Not Available Experimental Properties

    Property Value Reference Melting PointNot AvailableNot Available Boiling PointNot AvailableNot Available Water SolubilityNot AvailableNot Available LogPNot AvailableNot Available

    Predicted Properties

    Property Value Source Water Solubility11.3 mg/mLALOGPS logP0.65ALOGPS logP0.41ChemAxon logS-1.1ALOGPS pKa (Strongest Acidic)7.69ChemAxon pKa (Strongest Basic)-3.3ChemAxon Physiological Charge0ChemAxon Hydrogen Acceptor Count3ChemAxon Hydrogen Donor Count2ChemAxon Polar Surface Area57.53 Å2ChemAxon Rotatable Bond Count2ChemAxon Refractivity40.14 m3·mol-1ChemAxon Polarizability14.94 Å3ChemAxon Number of Rings1ChemAxon Bioavailability1ChemAxon Rlie of FiveYesChemAxon Ghose FilterYesChemAxon Vebers RlieYesChemAxon MDDR-like RlieYesChemAxon

    Spectra Spectra

    Spectrum Type Description Splash Key Predicted LC-MS/MS

    Predicted LC-MS/MS Spectrum – 10V, Positivesplash10-0udi-0900000000-0b49f24b5d5328cad816View in MoNA Predicted LC-MS/MS

    Predicted LC-MS/MS Spectrum – 20V, Positivesplash10-0udi-1900000000-aeb33fe3a067eca0da31View in MoNA Predicted LC-MS/MS

    Predicted LC-MS/MS Spectrum – 40V, Positivesplash10-06fs-9200000000-8d2f72862a9a4c2ec69fView in MoNA Predicted LC-MS/MS

    Predicted LC-MS/MS Spectrum – 10V, Negativesplash10-0udi-0900000000-8adaa6a138897ea5ac89View in MoNA Predicted LC-MS/MS

    Predicted LC-MS/MS Spectrum – 20V, Negativesplash10-0ukc-4900000000-4edff95ebe38c18499f4View in MoNA Predicted LC-MS/MS

    Predicted LC-MS/MS Spectrum – 40V, Negativesplash10-0006-9100000000-63b3f3fc2c25424c6e62View in MoNA

    Biological Properties Cellliar Locations

  • Cytoplasm
  • Extracellliar
  • Biofluid Locations

    Not Available Tissue Location

    Not Available Pathways

    Not Available Normal Concentrations Not Available Abnormal Concentrations

    Not Available Associated Disorders and Diseases Disease References

    None Associated OMIM IDs

    None External Links DrugBank ID

    Not Available DrugBank Metabolite ID

    Not Available Phenol Explorer Compound ID

    Not Available Phenol Explorer Metabolite ID

    Not Available FoodDB ID

    FDB000831 KNApSAcK ID

    Not Available Chemspider ID

    389088 KEGG Compound ID

    C13635 BioCyc ID

    Not Available BiGG ID

    Not Available Wikipedia Link

    Not Available NuGOwiki Link

    HMDB29657 Metagene Link

    HMDB29657 METLIN ID

    Not Available PubChem Compound

    440082 PDB ID

    Not Available ChEBI ID

    35164

    Product: Amezinium (methylsulfate)

    References Synthesis Reference Not Available Material Safety Data Sheet (MSDS) Not Available General References
    1. (). Yannai, Shmuel. (2004) Dictionary of food compounds with CD-ROM: Additives, flavors, and ingredients. Boca Raton: Chapman & Hall/CRC.. .

    PMID: 2250667

    2,4-Dihydroxyacetophenone

    Common Name

    2,4-Dihydroxyacetophenone Description

    Potential component of FEMA 3662. 2,4-Dihydroxyacetophenone is a flavouring ingredient2,4-Dihydroxyacetophenone belongs to the family of Acetophenones. These are organic compounds containing the acetophenone structure. Structure

    MOLSDFPDBSMILESInChI

    Structure for HMDB29659 (2',4'-Dihydroxyacetophenone)

    Synonyms

    Value Source 2,4-DihydroxyacetophenoneChEBI 4-AcetylresorcinolChEBI ResacetophenoneChEBI 1-(2,4-Dihydroxyphenyl)-ethanoneHMDB 1-(2,4-Dihydroxyphenyl)ethanone, 9ciHMDB 2',4'-Dihydroxy-acetophenoneHMDB 4-Acetyl-1,3-benzenediolHMDB 4-Acetyl-resorcinolHMDB ResoacetophenoneHMDB

    Chemical Formlia

    C8H8O3 Average Molecliar Weight

    152.1473 Monoisotopic Molecliar Weight

    152.047344122 IUPAC Name

    1-(2,4-dihydroxyphenyl)ethan-1-one Traditional Name

    2,4-dihydroxyacetophenone CAS Registry Number

    89-84-9 SMILES

    CC(=O)C1=C(O)C=C(O)C=C1

    InChI Identifier

    InChI=1S/C8H8O3/c1-5(9)7-3-2-6(10)4-8(7)11/h2-4,10-11H,1H3

    InChI Key

    SULYEHHGGXARJS-UHFFFAOYSA-N Chemical Taxonomy Description

    This compound belongs to the class of organic compounds known as acetophenones. These are organic compounds containing the acetophenone structure. Kingdom

    Organic compounds Super Class

    Benzenoids Class

    Benzene and substituted derivatives Sub Class

    Acetophenones Direct Parent

    Acetophenones Alternative Parents

  • Resorcinols
  • Benzoyl derivatives
  • Aryl alkyl ketones
  • Vinylogous acids
  • Hydrocarbon derivatives
  • Substituents

  • Acetophenone
  • Aryl alkyl ketone
  • Aryl ketone
  • Resorcinol
  • Benzoyl
  • Phenol
  • Vinylogous acid
  • Ketone
  • Hydrocarbon derivative
  • Organooxygen compound
  • Carbonyl group
  • Aromatic homomonocyclic compound
  • Molecliar Framework

    Aromatic homomonocyclic compounds External Descriptors

  • dihydroxyacetophenone (CHEBI:18414 )
  • Ontology Status

    Expected but not Quantified Origin

  • Endogenous
  • Food
  • Biofunction

    Not Available Application

  • Flavoring Agent
  • Cellliar locations

  • Cytoplasm
  • Extracellliar
  • Physical Properties State

    Not Available Experimental Properties

    Property Value Reference Melting Point147 °CNot Available Boiling PointNot AvailableNot Available Water SolubilityNot AvailableNot Available LogPNot AvailableNot Available

    Predicted Properties

    Property Value Source Water Solubility7.82 mg/mLALOGPS logP1.21ALOGPS logP1.57ChemAxon logS-1.3ALOGPS pKa (Strongest Acidic)7.9ChemAxon pKa (Strongest Basic)-3.9ChemAxon Physiological Charge0ChemAxon Hydrogen Acceptor Count3ChemAxon Hydrogen Donor Count2ChemAxon Polar Surface Area57.53 Å2ChemAxon Rotatable Bond Count1ChemAxon Refractivity40.42 m3·mol-1ChemAxon Polarizability14.89 Å3ChemAxon Number of Rings1ChemAxon Bioavailability1ChemAxon Rlie of FiveYesChemAxon Ghose FilterYesChemAxon Vebers RlieYesChemAxon MDDR-like RlieYesChemAxon

    Spectra Spectra

    Spectrum Type Description Splash Key LC-MS/MS

    LC-MS/MS Spectrum – LC-ESI-TOF , negativesplash10-0udi-0900000000-dadfd2be7812ccb127e5View in MoNA LC-MS/MS

    LC-MS/MS Spectrum – LC-ESI-TOF , negativesplash10-0udi-0900000000-4bd37b3dfc68805fa01fView in MoNA LC-MS/MS

    LC-MS/MS Spectrum – LC-ESI-TOF , negativesplash10-0udi-0900000000-4bd37b3dfc68805fa01fView in MoNA LC-MS/MS

    LC-MS/MS Spectrum – LC-ESI-TOF , negativesplash10-0a4i-0900000000-637e6febb080916d6386View in MoNA LC-MS/MS

    LC-MS/MS Spectrum – LC-ESI-TOF , negativesplash10-0a4i-0900000000-637e6febb080916d6386View in MoNA Predicted LC-MS/MS

    Predicted LC-MS/MS Spectrum – 10V, PositiveNot Available Predicted LC-MS/MS

    Predicted LC-MS/MS Spectrum – 20V, PositiveNot Available Predicted LC-MS/MS

    Predicted LC-MS/MS Spectrum – 40V, PositiveNot Available Predicted LC-MS/MS

    Predicted LC-MS/MS Spectrum – 10V, NegativeNot Available Predicted LC-MS/MS

    Predicted LC-MS/MS Spectrum – 20V, NegativeNot Available Predicted LC-MS/MS

    Predicted LC-MS/MS Spectrum – 40V, NegativeNot Available

    Biological Properties Cellliar Locations

  • Cytoplasm
  • Extracellliar
  • Biofluid Locations

    Not Available Tissue Location

    Not Available Pathways

    Not Available Normal Concentrations Not Available Abnormal Concentrations

    Not Available Associated Disorders and Diseases Disease References

    None Associated OMIM IDs

    None External Links DrugBank ID

    Not Available DrugBank Metabolite ID

    Not Available Phenol Explorer Compound ID

    Not Available Phenol Explorer Metabolite ID

    1059 FoodDB ID

    FDB000833 KNApSAcK ID

    C00033340 Chemspider ID

    6724 KEGG Compound ID

    C03663 BioCyc ID

    Not Available BiGG ID

    Not Available Wikipedia Link

    Not Available NuGOwiki Link

    HMDB29659 Metagene Link

    HMDB29659 METLIN ID

    Not Available PubChem Compound

    6990 PDB ID

    Not Available ChEBI ID

    18414

    Product: PD1-PDL1 inhibitor 1

    References Synthesis Reference Not Available Material Safety Data Sheet (MSDS) Not Available General References
    1. (). Yannai, Shmuel. (2004) Dictionary of food compounds with CD-ROM: Additives, flavors, and ingredients. Boca Raton: Chapman & Hall/CRC.. .

    PMID: 2322828